Lets prove this for a more general case $Y=X\beta+\varepsilon$, where $Y$ is a vector of observations $X$ is the model or design matrix, $\beta$ is a vector of regression coefficients and $\varepsilon\sim N(0,\sigma^{2}I_{n})$ is a multivariate normal. Then for a single observation $Y_{i}=X_{1}\beta_{1}+X_{2}\beta_{2}...+\varepsilon_{i}$. The OLS which also happens to be the MLE in the normal error case is given by
$\hat\beta=(X'X)^{-1}X'Y$
$Var[\hat\beta]=Var[(X'X)^{-1}X'Y]=(X'X)^{-1}X'Var[Y]X(X'X)^{-1}=\sigma^{2}(X'X)^{-1}X'I_{n}X(X'X)^{-1}=\sigma^{2}(X'X)^{-1}$
so for a single regression coefficient, $Var[\hat\beta_{i}]=\sigma^{2}(X'X)^{-1}_{ii}$.
That is a more general proof. In your case you only have one column in your model/design matrix, so
$Var[\hat\beta_{i}]=\frac{\sigma_{2}}{X'X}=\frac{\sigma_{2}}{\sum_{}x_{i}^{2}}$