My favourite example of a surprising fact in hyperbolic geometry is the following:
Every triangle in the hyperbolic plane $\mathbb{H}$ has area less than or equal to $\pi$. Further, any ideal triangle (a triangle with vertices on the boundary $\partial\mathbb{H}$) has area equal to $\pi$.
This is an immediate consequence of the Gauss-Bonnet theorem which, in the hyperbolic case, can be proved without needing the full machinery of differential geometry.
For general Riemannian manifolds, the Guass-Bonnet theorem says:
General Gauss-Bonnet. Let $M$ be a compact $2$-dimensional Riemannian manifold with boundary $\partial M$ and let $K$ be the Gaussian curvature of $M$ and $k_g$ be the geodesic curvature of $\partial M$. Then $$\int_M K\, dA+\int_{\partial M} k_g\, ds=2\pi\chi(M)$$ where $dA$ is an area element, $ds$ is a line element on the boundary, and $\chi(M)$ is the Euler characteristic of $M$.
In the hyperbolic case for triangles, this reduces to:
Hyperbolic Gauss-Bonnet for triangles. Let $\Delta$ be a hyperbolic triangle with internal angles $\alpha,\beta,\gamma$. Then $$\mbox{Area}_{\mathbb{H}}(\Delta)=\pi-(\alpha+\beta+\gamma).$$
The remarkable implication of this theorem is that the area of a hyperbolic triangle is fully determined by its angles (in stark contrast to the case of triangles in Euclidean space) and that, because angles are non-negative (they can be zero if vertices are on the boundary), then we see that $\pi$ is an upper limit for the area of any triangle in $\mathbb{H}$ (also in stark contrast to the case of triangles in Euclidean space). This bound is then tight, and attained by any triangle with all three vertices on the boundary of $\mathbb{H}$ which means $\alpha+\beta+\gamma=0+0+0$.
This is surprising mostly because the area of the entire hyperbolic plane is unbounded and so, unlike the sphere for example, we might expect that triangles can be formed with arbitrarily large area by simply pushing vertices further and further away from each other. The Gauss-Bonnet theorem though says that this is not the case, and in fact pushing vertices away from each other has less and less effect the more they are moved, even infinitely far away from each other.
Of course, any convex hyperbolic polygon can be partitioned into a minimal number of triangles, and so this also gives bounds on the area of such polygons (can you see what the bound would be for a polygon with $E$ edges and internal angles $\gamma_1,\ldots\gamma_{E}$?)
For a well written proof of the Gauss-Bonnet theorem for hyperbolic triangles which does not rely on the general theorem (it uses nothing more than basic double integration and the theory of Mobius transformations) I would recommend the following page of lecture notes provided on Charles Walkden's webpage.