Suppose that $L$ is context-free, let $p$ be the pumping length, and let $w=0^{3(p+1)}1^{p+1}$. By the pumping lemma we can write $w=uvxyz$, where $|vxy|\le p$, $|vy|\ge 1$, and $uv^kxy^kz\in L$ for each $k\ge 0$.
Let $r$ be the number of $0$’s in $vy$, and $s$ the number of $1$’s. Note that if either $v$ or $y$ contains both $0$’s and $1$’s, then $uv^2xy^2z$ has at least one $1$ preceding a $0$ and cannot be in $L$, so we may assume that $v=0^r$ and $y=1^s$. Thus, $$uv^kxy^kz=0^{3(p+1)+(k-1)r}1^{p+1+(k-1)s}$$ for each $k\ge 0$.
If $r<s$, then for sufficiently large $k$ the word $uv^kxy^kz$ has more $1$’s than $0$’s and cannot be in $L$, so we must have $r\ge s$. The excess of $0$’s over $1$’s in $uv^kxy^kz$ is
$$\big(3(p+1)+(k-1)r\big)-\big(p+1+(k-1)s\big)=2(p+1)+(k-1)(r-s)\;,$$
and in order for $uv^kxy^kz$ to be in $L$, this must be a multiple of $p+1+(k-1)s$, the number of $1$’s. That is, for each $k\ge 0$ we must have
$$\frac{2(p+1)+(k-1)(r-s)}{p+1+(k-1)s}\in\Bbb Z\;.\tag{1}$$
If $r-s<s$ this is impossible: for sufficiently large $k$ the denominator of $(1)$ will exceed the numerator. Thus, we must have $r=2s$, so that the excess of $0$’s over $1$’s in $uv^kxy^kz$ is $$2(p+1)+(k-1)s\;,$$ and
$$\frac{2(p+1)+(k-1)s}{p+1+(k-1)s}\in\Bbb Z$$
for each $k\ge 0$, where $0<s<p$. Can you see why this is impossible? There’s a hint in the spoiler-protected block below, if you need one.
What happens in the limit as $k\to\infty$?