Suppose that $V$ and $W$ are 2 finite dimensional vectors spaces and $T$ is a linear transformation such that $T : V \rightarrow W$. Then $T \rightarrow T^t$ can be seen as an isomorphism of $L(V,W)$ into $L(W^\ast,V^\ast)$.
Now suppose that $V$ and $W$ are infinite dimensional vector spaces, can a transpose exist and is there an isomorphism?