Hint: at a minimum of a function, the derivative is zero.
Newton-Rhapson is a root-finding algorithm, and hence is well-suited to computing zeros of functions.
Edit: You need to find the minimum. The first step of this is to find points where $\frac{\partial f}{\partial x_1}$ and $\frac{\partial f}{\partial x_2}$ are both zero.
Now you have two conditions, so you want to compute:
$$\mathbf{g}(x_1,x_2) \stackrel{\textrm{def}}{=}\begin{pmatrix} \frac{\partial f}{\partial x_1} \\ \frac{\partial f}{\partial x_2} \end{pmatrix} = \begin{pmatrix} 0 \\ 0 \end{pmatrix}.$$
This gives you two equations with two unknowns. Now perform Newton-Raphson on $\mathbf{g}$. The "Jacobian" of $\mathbf{g}$ is the Hessian of $f$, so you'll have a matrix that looks like:
$$\begin{pmatrix} \frac{\partial^2 f}{\partial x_1^2} & \frac{\partial^2 f}{\partial x_1 \partial x_2} \\ \frac{\partial ^2 f}{\partial x_2\partial x_1} & \frac{\partial^2 f}{\partial^2 x_2}\end{pmatrix}$$