Doeblin's theorem states that for a given transition probability matrix there exists a unique invariant distribution for that chain.
Is the converse true as well? Can two (finite state, discrete) Markov Chains have the same invariant distribution, but have different transition matrices?
I don't think so, but I have only tried a proof by contradiction:
Assume there are two transition matrices, P and Q such that $\pi$ P = $\pi$ and $\pi$Q = $\pi$ ($\pi$ is the invariant distribution). Then $\pi$ P = $\pi$Q and P=Q (contradiction).
However, this doesn't really tell me why this should be true.