The Trace Theorem in Evan's Book (1st edition) says that,
Assume $U$ is bounded and $\partial U$ is $C^1$. Then there exsits a bounded linear operator $T$, $$T:W^{1,p}(U)\rightarrow L^p(U)$$ such that,
(i) $Tu=u|_{\partial U}$ if $u\in W^{1,p}(U)\cap C(U)$,
and
(ii) $\|Tu\|_{L^p(\partial U)} \le C \| u \|_{W^{1,p}(U)}$.
for each $u\in W^{1,p}(U)$, with the constant $C$ depending only on $p$ and $U$.
I am interested in the uniqueness. Does there exist different operators $T_1$ and $T_2$ which satisfy the condition in the Trace Theorem ? This theorem does not answer this question.
If yes, then we cannot define $Tu$ as the trace of $u$ on $\partial U$.