Let $\begin{cases}x=\dfrac{\xi+\tau}{2}\\t=\dfrac{\xi-\tau}{2}\end{cases}$ ,
Then $\dfrac{\partial u}{\partial\tau}=\dfrac{\partial u}{\partial x}\dfrac{\partial x}{\partial\tau}+\dfrac{\partial u}{\partial t}\dfrac{\partial t}{\partial\tau}=\dfrac{1}{2}\dfrac{\partial u}{\partial x}-\dfrac{1}{2}\dfrac{\partial u}{\partial t}$
$\dfrac{\partial^2u}{\partial\xi\partial\tau}=\dfrac{\partial}{\partial\xi}\left(\dfrac{1}{2}\dfrac{\partial u}{\partial x}-\dfrac{1}{2}\dfrac{\partial u}{\partial t}\right)=\dfrac{\partial}{\partial x}\left(\dfrac{1}{2}\dfrac{\partial u}{\partial x}-\dfrac{1}{2}\dfrac{\partial u}{\partial t}\right)\dfrac{\partial x}{\partial\xi}+\dfrac{\partial}{\partial t}\left(\dfrac{1}{2}\dfrac{\partial u}{\partial x}-\dfrac{1}{2}\dfrac{\partial u}{\partial t}\right)\dfrac{\partial t}{\partial\xi}=\dfrac{1}{2}\biggl(\dfrac{1}{2}\dfrac{\partial^2u}{\partial x^2}-\dfrac{1}{2}\dfrac{\partial^2u}{\partial x\partial t}\biggr)+\dfrac{1}{2}\biggl(\dfrac{1}{2}\dfrac{\partial^2u}{\partial x\partial t}-\dfrac{1}{2}\dfrac{\partial^2u}{\partial t^2}\biggr)=\dfrac{1}{4}\dfrac{\partial^2u}{\partial x^2}-\dfrac{1}{4}\dfrac{\partial^2u}{\partial t^2}$
$\therefore\dfrac{1}{4}\dfrac{\partial^2u}{\partial x^2}-\dfrac{1}{4}\dfrac{\partial^2u}{\partial t^2}=-e^u$
$\dfrac{\partial^2u}{\partial t^2}=\dfrac{\partial^2u}{\partial x^2}+4e^u$
This is a PDE of the form http://eqworld.ipmnet.ru/en/solutions/npde/npde2103.pdf.
It has the general solution $u(x,t)=f(x-t)+g(x+t)-2\ln\left(k\int^{x-t}e^{f(r)}~dr-\dfrac{1}{2k}\int^{x+t}e^{g(s)}~ds\right)$
$\therefore u(\xi,\tau)=f(\tau)+g(\xi)-2\ln\left(k\int^\tau e^{f(r)}~dr-\dfrac{1}{2k}\int^\xi e^{g(s)}~ds\right)$