Let's address your question 1 first. Recall that in part a you found that $\{\mathbf{v},\ \mathbf{w}\}$ forms a basis for the columnspace of $A$. The reason that the argument works for $\mathbf{u}$ and not for $\mathbf{v}$ is because $\mathbf{u}$ is not an element of this basis set while $\mathbf{v}$ is. Analagously, the argument will also fail for $\mathbf{w}$ (and indeed any linear combination of $\mathbf{v}$ and $\mathbf{w}$).
Since $\{\mathbf{u},\ \mathbf{v},\ \mathbf{w}\}$ was assumed to be linearly independent, it follows that $\mathbf{u}$ is not in the span of $\mathbf{v}$ and $\mathbf{w}$. Otherwise, there exists scalars $a$ and $b$ such that
$$a\mathbf{v} + b\mathbf{w} = \mathbf{u}$$
But then we have the non-trivial linear combination
$$a\mathbf{v} + b\mathbf{w} - \mathbf{u} = \mathbf{0}$$
contrary to the assumption of linear independence.
Since the span of $\mathbf{v}$ and $\mathbf{w}$ is precisely $\mathrm{col}(A)$, this means that $\mathbf{u}$ is not an element of the columnspace, i.e. there does not exist $\mathbf{x}$ such that $A\mathbf{x} = \mathbf{u}$. Note that this argument cannot work for $\mathbf{v}$ because $\mathbf{v}$ is in the span of $\{\mathbf{v},\ \mathbf{w}\}$, and trivially so.
For question 2, the geometric intuition is complicated by the fact that there do exist matrices in which vectors in the nullspace are also in the columspace (i.e. matrices for which part b has a solution). In fact, there exists matrices in which the columnspace is equal to the nullspace, for example
$$A = \begin{pmatrix}0 & 1 \\ 0 & 0\end{pmatrix}$$
However, for diagonalizable matrices (such as the one in consideration), we can present a relatively simple view. If you have not learned about diagonalization yet, then it may be difficult to follow the next bit. I recommend that you continue with your studies for now; diagonalization is typically not far away once you've begun studying eigenvectors and eigenvalues. You can come back to the next part after you've learned about diagonalization.
When your matrix is diagonalizable, you can effectively view the matrix as a sequence of scalings along the standard axes (via a change of basis). With this viewpoint, we can effectively look at $A$ as a linear transformation in 3-space where the $x$-axis is stretched by a factor of $3$ (representing the basis vector $\mathbf{v}$), where the $y$-axis is stretched by a factor of $5$ (representing $\mathbf{w}$), and where the $z$-axis is compressed (representing $\mathbf{u}$).
From this viewpoint, the statement that $\mathbf{u}$ is not in the columnspace is analagous to the statement that the image of the linear transform does not contain the $z$-axis, but this is intuitively obvious since the mapping compresses $z$. In fact, it's relatively clear from our description that the image of the map is entirely contained within the $z=0$ plane, i.e. the $xy$-plane. This is a representation of the fact that the columnspace of $A$ does not contain any vectors in which $\mathbf{u}$ is a component, i.e. $a\mathbf{v} + b\mathbf{w} + c\mathbf{u}$ is not an element of $\mathrm{col}(A)$ if $c\neq 0$.
Addendum for the supplementary questions by the OP
Question 3: Why consider $c_1\mathbf{v} + c_2\mathbf{w}$ for the columnspace?
The consideration of linear combinations of $\mathbf{v}$ and $\mathbf{w}$ comes from experience with eigenvalues. The key point is the hidden assumption that the matrix is $3\times 3$ which is not stated in the text of the question for some reason. Since $A$ is $3\times 3$ with $3$ distinct eigenvalues, this means that $A$ is diagonalizable, as I mentioned previously. What this means in particular is that the eigenvectors $\mathbf{u},\ \mathbf{v}$ and $\mathbf{w}$ forms a basis for $\mathbb{R}^3$ (assuming $A$ is a real matrix). If we consider some arbitary vector in $\mathbb{R}^3$, then it follows that we can write $\mathbf{x}$ as a linear combination of our basis of eigenvectors or eigenbasis:
$$\mathbf{x} = c_1\mathbf{v} + c_2\mathbf{w} + c_3\mathbf{u}$$
If we then consider the image of $\mathbf{x}$ under $A$, we get
$$A\mathbf{x} = c_1A\mathbf{v} + c_2A\mathbf{w} + c_3A\mathbf{u} = 3c_1\mathbf{v} + 5c_2\mathbf{w}$$
Since our choice of $\mathbf{x}$ is completely arbitrary, it follows that the entire image of $A$, that is the entire columnspace of $A$, is expressible as a linear combination of $\mathbf{v}$ and $\mathbf{w}$. Conversely, the solution for part (a) shows that every such linear combination is indeed in the columnspace.
As for question 4, I'm also not too sure what the solution is trying to do. It seems that part (b) in the question is answered by part (c) in the solution and that part (b) of the solution is completely extraneous. It seems to answer a different question altogether.
Addendum 2 in response to OP's questions
The fact that $\mathbf{u}\notin \mathrm{span}(\mathbf{v},\ \mathbf{w})$ comes simply from the fact that $\{\mathbf{u},\ \mathbf{v},\ \mathbf{w}\}$ is a linearly independent set. Certainly you can recast the argument so that contradiction is not used, and here is one example of a proof using the contrapositive instead of contradiction. This proof makes it clear that the result follows essentially from the definition of linear independence.
Theorem: Suppose that $\{\mathbf{v}_1,\ \cdots,\ \mathbf{v}_n\}$ is a linearly independent set of vectors. Then $\mathbf{v}_1 \notin \mathrm{span}(\mathbf{v}_2,\ \cdots,\ \mathbf{v}_n)$.
Proof: The contrapositive of the statement is: Suppose that $\mathbf{v}_1 \in \mathrm{span}(\mathbf{v}_2,\ \cdots,\ \mathbf{v}_n)$. Then $\{\mathbf{v}_1,\ \cdots,\ \mathbf{v}_n\}$ is linearly dependent.
But this is essentially trivial. The fact that $\mathbf{v}_1 \in \mathrm{span}(\mathbf{v}_2,\ \cdots,\ \mathbf{v}_n)$ means there exists some linear combination of $\{\mathbf{v}_2,\ \cdots,\ \mathbf{v}_n\}$ adding up to $\mathbf{v}_1$, i.e. there exists scalars $\{c_i\}$ such that
$$\mathbf{v}_1 = c_2\mathbf{v}_2 + \cdots + c_n\mathbf{v}_n$$
But then we also have
$$-\mathbf{v}_1 + c_2\mathbf{v}_2 + \cdots + c_n\mathbf{v}_n = \mathbf{0}$$
which is a non-trivial linear combination of $\{\mathbf{v}_1,\ \cdots,\ \mathbf{v}_n\}$ adding up to the zero vector. By definition, this means that $\{\mathbf{v}_1,\ \cdots,\ \mathbf{v}_n\}$ is linearly dependent. $\square$
Applying this result to the set $\{\mathbf{u},\ \mathbf{v},\ \mathbf{w}\}$ gives the desired result.
Note that the above argument works for any set of linearly independent vectors. However, we can also take advantage of the fact that $\{\mathbf{u},\ \mathbf{v},\ \mathbf{w}\}$ are eigenvectors under distinct eigenvalues to prove that they are linearly independent. This results in the well known theorem that eigenvectors corresponding to distinct eigenvalues are linearly independent. The proof of this fact is available in many, many locations and so I will not reproduce it here. I simply wanted to let you know of an alternative approach which you may prefer instead.