I know that zero pint of $\tan$ is $n\pi $, and for $\cos$ is
$\frac{\pi}{2}+n\pi$.
These facts alone are irrelevant for your question because on the left side of your equation you are summing the terms $2\cos x$ and $-3\tan x$. It would be very useful if you had a product of two factors, e.g.
$$(2\cos x)(-3\tan x)=0.$$
Then the zeros of this equation would be the zeros of $2\cos x=0$ and the zeros of $-3\tan x=0$.
Concerning your equation let us transform it into an equivalent one, e.g. as follows
\begin{eqnarray*}
2\cos x-3\tan x &=&0 \tag {1}\\
&\Leftrightarrow &2\cos x-3\frac{\sin x}{\cos x}=0,\qquad \cos x\neq 0 \\
&\Leftrightarrow &2\cos ^{2}x-3\sin x=0 \\
&\Leftrightarrow &2-2\sin ^{2}x-3\sin x=0.\tag {2}
\end{eqnarray*}
Let $y=\sin x$. Then
\begin{equation*}
2-2y^{2}-3y=0\Leftrightarrow y=-2,y=\frac{1}{2}.\tag {3}
\end{equation*}
Since the solution $y=\sin x=-2$ is impossible, the problem is reduced to
finding the roots of
\begin{equation*}
\sin x=\frac{1}{2}.\tag {4}
\end{equation*}
The general solution of $(4) $ is $x=\frac{\pi }{6}+2k\pi$ and $x=\frac{5\pi }{6}+2k\pi$, with $k\in \mathbb{Z}$, because, in the interval $[0,2\pi]$, $\sin (x)=1/2$ at $x=\pi/6$ and $x=\pi-\pi/6=5\pi/6$, and not only the point $ x=\pi/6 $, as found by you, (see Wikipedia entry Trigonometric functions on the unit circle) and the sinus function is periodic with period equal to $2\pi$.
Alternatively look at the graph of $y=\sin(x)$ for $-2\pi\le x\le 2\pi$, and the horizontal line $y=1/2$, which crosses $ y=\sin (x) $ at the points mentioned above, and you can see the period of this trigonometric function.
