If the original statement is "if $P$, then $Q$," then the contrapositive statement is "If not $Q$, then not $P$." So, in your case, the original claim reads, "If $n$ is even, then $n^2$ is also even." The contrapositive would then read, "If $n^2$ is not even, then $n$ is not even," or equivalently (since if a number is not even, it is odd): "If $n^2$ is odd, then $n$ is odd." Let's prove this. If $n^2$ is odd, then $n^2 = 2m + 1$ for some (nonnegative) integer $m$. Then $2m = n^2 - 1 = (n-1)(n+1)$. But since the LHS is even, so must be the right. But $n-1$ and $n+1$ share the same parity--i.e., they are either both odd or both even. Since an odd number times an odd number is odd, it follows that $n-1$ is even, hence $n$ itself is odd.
It's an unnecessarily complicated proof, of course--for the direct proof is that if $n$ is even, then $n = 2m$ for some integer $m$, hence $n^2 = (2m)^2 = 4m^2$ which is obviously even.