Just to make one more observation about "almost impossible events". Consider the experiment of picking a random real number in the interval I := [0, 1) (say, but it's not really important, using an uniform random distribution) and the question "How probable is it that the picked number is rational"?
The set of non-rational numbers in I is uncountable, whereas the set of rational numbers in the same interval is countable. It means that the probability of picking a non-rational number is infinitely larger than that of picking a rational number and, consequently, the probability of picking a rational number is 0. However, nothing prevents you from picking 0.5, which is a perfectly possible result of your experiment.
As Dror points out, some events can have probability 0 and this does not mean that there is no possibility for them to occur.
What is the probability of an almost impossible event?
Mathematically speaking, it is 0.
"Almost" has a well-defined mathematical meaning. A function can be almost everywhere continuous, meaning that it is continuous everywhere but in a countable set of places. The Dirac Delta function is almost everywhere zero.
EDIT:
no, the explanation of "almost everywhere continuous" is not the one given in the last paragraph. The truth is more complex than this, and the linked Wikipedia article gives a correct explanation.