After some work here's my answer.
Begin with:
$$\phi:\Bbb R\to S^1\le\Bbb C^*\;,\;\;\phi(r):=e^{2\pi i r}$$
Then we want to show that $\phi$ is a group homomorphism between $\Bbb R$ and $S^1$.
Note: By Euler's formula, $e^{i\theta} = \cos\theta + i\sin\theta$.
First we prove that $\phi$ is surjective. This is easy to see since from our note $\sin$ and $\cos$ must span all possible values of a and b to give norm 1.
Again from our note it is clear that $\phi$ maps all integers to 1, the identity element of $S^1$. This is precisely $\ker(\phi)$.
Thus, by the first isomorphism theorem we have $(S^1, *)$ isomorphic to $\Bbb R / \Bbb Z$.