(New Solution)
This solution is much neater than the earlier solution (see below).
$$\begin{align}
S
&=\sum_{i=0}^{n-1}\sum_{j=0}^{i-1}\sum_{k=0}^{j-1}i+j+k=\color{lightgrey}{\sum_{i=2}^{n-1}\sum_{j=1}^{i-1}\sum_{k=0}^{j-1}i+j+k}\tag{1}\\
&=\sum_{r=0}^{n-1}\sum_{s=n-i\\\;=r+1}^{n-1}\sum_{t=n-j\\\;=s+1}^{n-1}3(n-1)-(r+s+t)
&&\scriptsize{r=n-1-i\\s=n-1-j\\ t=n-1-k}\\
&=\sum_{t=2}^{n-1}\sum_{s=1}^{n-1}\sum_{r=0}^{n-1}3(n-1)-(t+s+r)
&&\scriptsize 0\le r<s<t\le n-1\\
&=\sum_{i=2}^{n-1}\sum_{j=1}^{i-1}\sum_{k=1}^{j-1}3(n-1)-(i+j+k)\tag{2}\\
&=\frac 32(n-1)\sum_{i=2}^{n-1}\sum_{j=2}^{n-1}\sum_{k=0}^{n-1}1
&&\frac {(1)+(2)}2\\
&=\frac 32(n-1)\sum_{i=2}^{n-1}\sum_{j=2}^{n-1}\binom j1\\
&=\frac 32(n-1)\sum_{i=2}^{n-1}\binom i2\\
&=\color{red}{\frac 32(n-1)\binom n3}\\
&=\color{red}{\frac {n(n-1)^2(n-2)}4}\\
&=\color{red}{\binom {n-1}2\binom n2}
\end{align}$$
(Earlier solution below)
This solution arrives at the solution in the form of the product of two sums of integers.
$$\begin{align}
\sum_{i=0}^{n-1}\sum_{j=0}^{i-1}\sum_{k=0}^{j-1}(i+j+k)
&=\sum_{i=2}^{n-1}\sum_{j=1}^{i-1}\sum_{k=0}^{j-1}(i+j+k)\\
&=\sum_{i=2}^{n-1}\sum_{j=1}^{i-1}\sum_{s=1}^{j}(i+2j-s)
&&(s=j-k)\\
&=\sum_{i=2}^{n-1}\sum_{s=1}^{i-1}\sum_{j=s}^{i-1}(i+2j-s)
&&(1\le s\le j\le i-1)\\
&\color{lightgrey}{=\sum_{i=2}^{n-1}\sum_{s=1}^{i-1}(i-s)(i-s)+2\cdot \frac {i-s}2(s+\overline{i-1})}
&&\color{lightgrey}{\text{(number of steps=$i-s$)}}\\
&=\sum_{i=2}^{n-1}\sum_{s=1}^{i-1}(i-s)(i+\overline{i-1})\\
&=\sum_{i=2}^{n-1}\sum_{r=1}^{i-1}r(i+\overline{i-1})
&&(r=i-s)\\
&=\sum_{r=1}^{n-2}r\sum_{i=r+1}^{n-1}(i+\overline{i-1})
&&(1\le r<i\le n-1)\\
&=\sum_{r=1}^{n-2}r\sum_{i=r+1}^{n-1}i+\sum_{r=1}^{n-2}r\sum_{i=r+1}^{n-1}(i-1)\\
&=\sum_{r=1}^{n-2}r\sum_{i=r+1}^{n-1}i+\sum_{r=1}^{n-2}r\sum_{i=r}^{n-2}i\\
&=\sum_{r=1}^{n-2}r\sum_{i=r+1}^{n-1}i+\sum_{i=1}^{n-2}i\sum_{r=1}^{i}r
&&(1\leq r\le i\le n-2)\\
&=\sum_{i=1}^{n-2}i\sum_{r=i+1}^{n-1}r+\sum_{i=1}^{n-2}i\sum_{r=1}^{i}r\\
&=\sum_{i=1}^{n-2}i\left(\sum_{r=1}^i r+\sum_{r=i+1}^{n-1}r\right)\\
&=\sum_{i=1}^{n-2}i\sum_{r=1}^{n-1}r\\
&=\color{red}{\binom {n-1}2\binom n2}\\
&=\color{red}{\frac 14n(n-1)^2(n-2)}
\end{align}$$