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I have the following equation

$$ S = 3Nk\left[ ln \left( \frac{e^{\Theta/T}}{e^{\Theta/T}-1} \right) + \frac{\Theta/T}{e^{\Theta/T}-1} \right]$$

And I need to evaulate it in the limit as $T \rightarrow 0$.

I have used the approximation $e^{\Theta/T} \approx 1 + \frac{\Theta}{T}$ (Taylor Expansion to first order).

Using this and rearranging I get that $S \rightarrow 3Nk$ but this is incorrect.

The correct answer is:

$$S \rightarrow 3Nk\frac{\Theta}{T}e^{-\Theta/T} \rightarrow 0$$

Can you explain to me why? I must be missing something here.

EDIT: As one of you pointed out, my professor clearly meant: $$S \sim 3Nk\frac{\Theta}{T}e^{-\Theta/T} \rightarrow 0$$

turnip
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1 Answers1

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Hints:

  • Let $x=\Theta/T$ with $\Theta\gt0$. When $T\to0^+$, $x\to+\infty$.
  • When $x\to+\infty$, $\mathrm e^x/(\mathrm e^x-1)\to1$ hence $\log(\mathrm e^x/(\mathrm e^x-1))\to0$.
  • When $x\to+\infty$, $x/(\mathrm e^x-1)\to0$.
  • Ergo?
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