Actually, I just noticed that this is a duplicate. :'(
I'll leave my answer be for now.
@ScroogeMcDuck already gave an appropriate counterexample, but let me just elaborate a bit:
The following is a good thing to know:
Fact: $V = W\oplus W' \iff W+W' = V \text{ and } W\cap W' = \{0\}$
So, in our case, all we need to find as a counterexample to your "guess" is a $T: V\to V$ such that $\ker T \cap \operatorname{Im} T \neq \{0\}$. In fact, consider the example of "shift right" linear transformation $T: \mathbb{R}^2 \to \mathbb{R}^2$ given by $T(1,0)= (0,1), \ T(0,1) = (0,0)$. Well, clearly, $\ker T \cap \operatorname{Im} T = \operatorname{span}\{(0,1)\}\neq \{(0,0)\}$
A more higher view of this is the following (if you care):
Given a linear transformation $T: V\to V$, we have the following sequence of linear maps:
$$\ker T \overset{\text{inclusion}}\to V \overset{T}\to \operatorname{Im} T$$
Let's limit ourselves to $V$ being finite dimensional for simplicity. By just choosing basis for $\ker T$ and then extending it to the basis for $V$, you can see that $\ker T\oplus \operatorname{Im} T = V$ exactly means that the above sequence is a "short exact sequence" $0\to \ker T \to V\to \operatorname{Im} T\to 0$, which just means that image of each arrow is exactly the kernel of the next arrow. Your question is about splitting exact sequence of vector spaces, which has nice answers.