To find the probability that A throws more times than B, we need to sum the probabilities that A throws two or more times given that B throws once, A throws three or more times given that B throws twice and so on.
So we need to evaluate
$\sum_{k=1}^{\infty}P(A_{throws} > k,B_{throws}=k)$
Now for B throwing once, and A throwing two or more times, we have as probability (using the sum to infinity of a geometric progression)
$\large \frac{1}{6}\times\sum_{k=1}^{\infty}\left(\frac{5}{6}\right)^k\left(\frac{1}{6}\right)=\left(\frac{1}{6}\right)^2\left(\frac{\frac{5}{6}}{1-\frac{5}{6}}\right)=\frac{1}{6}\left(\frac{5}{6}\right)$
For B throwing twice, and A throwing three or more times, we have as probability (using the sum to infinity of a geometric progression as before)
$\large\left(\frac{5}{6}\right) \frac{1}{6}\times\sum_{k=2}^{\infty}\left(\frac{5}{6}\right)^k\left(\frac{1}{6}\right)=\left(\frac{5}{6}\right)\left(\frac{1}{6}\right)^2\left(\frac{\left(\frac{5}{6}\right)^2}{1-\frac{5}{6}}\right)=\frac{1}{6}\left(\frac{5}{6}\right)^3$
For B throwing three times, and A four or more times we have
$\large\left(\frac{5}{6}\right)^2 \frac{1}{6}\times\sum_{k=3}^{\infty}\left(\frac{5}{6}\right)^k\left(\frac{1}{6}\right)=\left(\frac{5}{6}\right)^2\left(\frac{1}{6}\right)^2\left(\frac{\left(\frac{5}{6}\right)^3}{1-\frac{5}{6}}\right)=\frac{1}{6}\left(\frac{5}{6}\right)^5$
Generalising for B throwing $m$ times and A throwing $m+1$ or more times, the probability is given by
$\large \frac{1}{6}\left(\frac{5}{6}\right)^{2m-1}$
Thus, the probability that A throws more times than B is given by the following scaled sum to infinity of a geometric progression with ratio $\left(\frac{5}{6}\right)^2$
$\large \sum_{k=1}^{\infty}P(A_{throws}>k,B_{throws}=k)=\frac{1}{6}\sum_{k=1}^{\infty}\left(\frac{5}{6}\right)^{2k-1}=\frac{1}{6}\frac{\frac{5}{6}}{1-\left(\frac{5}{6}\right)^2}=\frac{5}{11}$