Alright, here's another explanation.
The idea is that when you're dealing with an analytic function, if you know $f(a), f'(a), f''(a), ...$, then you already have all the information about $f$. If you also happen to know $f(b), f'(b), f''(b), ...$, well that information is totally redundant. Since
$$f(x) = f(a)+f'(a)\cdot(x-a)+\frac{1}{2!}f''(a)\cdot(x-a)^2+\cdots
= \sum_n \frac{f^{(n)}(a)}{n!}(x-a)^n$$
and
$$f^{(n)}(x) =
f^{(n)}(a) +
f^{(n+1)}(a)\cdot(x-a) +
\frac{1}{2!}f^{(n+2)}(a)\cdot(x-a)^2 +
\cdots =
\sum_m \frac{f^{(m)}(a)}{(m-n)!}(x-a)^{m-n},$$
just go into the series in question and substitute away all instances of $f^{(n)}(b)$. Then find the coefficient of $f^{(N)}(a)$ for each $N$; you'll find that you get $\frac{(b-a)^{N+1}}{(N+1)!}$ as the coefficient in both cases.
Are you prepared for gory details? Are you sure you really want to see gory details?
So the first series in question is
$$\sum_{n \ge 0}\frac{(b-a)^{n+1}}{(n+1)!}
\left( f^{(n)}(a) \cdot \frac12 + f^{(n)}(b) \cdot (-1)^n \cdot\frac12\right).$$
Now do the substitution to get
$$\sum_{n \ge 0}\frac{(b-a)^{n+1}}{(n+1)!}
\left( \frac12 f^{(n)}(a) + \frac12 (-1)^n
\sum_m \frac{f^{(m)}(a)}{(m-n)!}(b-a)^{m-n}
\right).$$
The coefficient of $f^{(N)}(a)$ in this
$$ \frac12 \frac{(b-a)^{N+1}}{(N+1)!} +
\frac12 (-1)^0 \frac{(b-a)^{0+1}}{(0+1)!} \frac{(b-a)^{N-0}}{(N-0)!} +
\frac12 (-1)^1 \frac{(b-a)^{1+1}}{(1+1)!} \frac{(b-a)^{N-1}}{(N-1)!} +
\cdots +
\frac12 (-1)^N \frac{(b-a)^{N+1}}{(N+1)!} \frac{(b-a)^{N-N}}{(N-N)!}
$$
which can be rewritten as
$$ \frac12 \frac{(b-a)^{N+1}}{(N+1)!}
\left(
1 +
(-1)^0 \binom{N+1}{1} +
\cdots +
(-1)^N \binom{N+1}{N+1}
\right)
.$$
Apply the binomial coefficient identity (i.e. just the binomial theorem)
$$ (-1)^0 \binom{c}{0} +
(-1)^1 \binom{c}{1} +
\cdots +
(-1)^c \binom{c}{c}
= (1-1)^c
= 0
$$
to get $\frac{(b-a)^{N+1}}{(N+1)!}$ as promised.
I'll leave out the details of the other verification; you my dear reader can fill them in as an exercise. To briefly sketch it: at the last step you'll get
$$ \frac{(b-a)^{N+1}}{(N+1)!}
\left(
\frac{1}{2^{N+1}} +
\frac{(-1)^0}{2^1}\binom{N+1}{1} +
\frac{(-1)^1}{2^2} \binom{N+1}{2} +
\cdots +
\frac{(-1)^N}{2^{N+1}} \binom{N+1}{N+1}
\right)
$$
and another binomial coefficient identity will bring you to $\frac{(b-a)^{N+1}}{(N+1)!}$.
So there it is. Hey, it wasn't actually so bad. I'd say the other proof is more intuitive, since it actually explains what the two series in question represent. This derivation is more straightforward, in the sense that it requires no real creative leaps.