Having invested a little energy in the formulation of this question (see comments), guess I'll spend a little more on an answer:
I'm in the Intermediate Value Theorem school on this one.
Before proceeding further, lauds and "+1" to breeden for an answer based on fundamental properties of the real number system $\Bbb R$. In the following, I have presented two arguments, one using the derivative of $r^n$ and one which only uses mere continuity, in order to make clear that differentiation is not essential in order to establish the desired results, though it does make things a little easier. Of course, the IVT is itself pretty close to the fundamentals of $\Bbb R$, depending as it does on the completeness of $\Bbb R$ (see this wikipedia page).
Having said these things, the setup is:
Let $\Bbb R_{0+}$ denote the non-negative real numbers; that is
$\Bbb R_{0+} = \{ y \in \Bbb R \mid y \ge 0 \}, \tag{1}$
and for $n \in \Bbb N$, let $f_n:\Bbb R_{0+} \to \Bbb R_{0+}$ be defined by $f_n(r) = r^n$; we have $f_n(0) = 0$ for all $n$. Given $x > 0$, it is easy to see that there exists $y \in \Bbb R_{0+}$ with $f_n(y) = y^n > x$; if there is any doubt about this, just choose $m$ to be any integer satisfying $m > x + 1$; then $m^n \ge m > x$; set $y = m$. Next, we note that $f_n(r)$ is continuous for all $n \in \Bbb N$; there are two ways to see this, the "with-derivatives" way and the (you guessed it!) "without-derivatives" way:
A.) with-derivatives: note that $f_n(r) = r^n$ is differentiable, $f_n'(r) = nr^{n - 1}$; being differentiable, it is continuous;
B.) without-derivatives: observe that for $r_0, r \in \Bbb R_{0+}$ with $r_0, r < L$,
$\vert r^n - r_0^n \vert = \vert (r - r_0)\sum_0^{n - 1}r^{n - 1 - i}r_0^i \vert$
$= \vert r - r_0 \vert \sum_0^{n - 1} r^{n - 1 - i}r_0^i < nL^{n - 1}\vert r - r_0 \vert, \tag{2}$
which shows that $r^n \to r_0^n$ as $r \to r_0$; thus, $f_n(r)$ is continuous.
We see from the above that $f_n(r)$ is continuous for each $n \in \Bbb N$, and that $f_n(0) < x < f_n(m)$; thus by the IVT there exists $r \in \Bbb R_{0+}$ with $r^n = x$; $r > 0$ since $x > 0$.
We proceed to show that $r$ is unique, in both the "with-derivatives" and the "without-derivatives" ways:
C.) with-derivatives: as we have seen in item (A), $f'_n(r) = nr^{n - 1}$; since $f_n'(r) > 0$ for $r > 0$, $f_n(r)$ is monotonically increasing on $\Bbb R_{0+}$; thus, given $r$ such that $f_n(r) = r^n =x > 0$, as $r$ increases (or decreases), $f_n(r)$ can never revisit $x$; to put it more formally, if $r_1^n = r_2^n = x$ with $r_1 \ne r_2$, we may take $r_2 > r_1$; but then $r_2^n > r_1^n$ by monotonicity, so if $r_1^n = x$, we must have $r_2^n > x$; likewise if $r_2 < r_1$, $f_n(r_2) < f_n(r_1) = x$; either alternative contradicts $r_1^n = r_2^n = x$; thus $r^n = x$ has a unique solution for $x \in \Bbb R_{0+}$;
D.) without-derivatives: the monotonicity of $f_n(r) = r^n$ can also be established by a simple demonstration based upon the binomial expansion of $(r + h)^n$ for $r, h \in \Bbb R_{0+}$; for we have
$(r + h)^n = \sum_0^n C_i^n r^{n - i}h^i = r^n + \sum_1^n C_i^n r^{n - i}h^i > r^n, \tag{3}$
since every term in $\sum_1^n C_i^n r^{n - i}h^i$ is positive. Given that $f_n(r) = r^n$ is monotonically increasing, we complete the argument for the uniqueness of $r$ satisfying $r^n = x$ as in (C).
Hope this helps! Cheerio,
and as always,
Fiat Lux!!!