A standard way to compare two (sufficiently nice) functions $f(x)$ and $g(x)$ over the interval $[a,b]$ is to use the inner product $$\left<f(x),g(x)\right>:=\int_a^b{f(x)g(x)\,\mathrm{d}x}$$ from which we get $$||f(x)-g(x)||=\sqrt{\int_a^b{\left(f(x)-g(x)\right)^2\,\mathrm{d}x}}$$ where you can think of $||f(x)-g(x)||$ as being the "distance" between the functions $f$ and $g$.
If you are dealing with parametric curves you could use $$\text{dist}\,\left(x(t),y(t)\right):=\sqrt{\int_{t_0}^{t_1}{||x(t)-y(t)||^2\,\mathrm{d}t}}$$ to get a reasonable measure, but you would have to ensure that both curves are parameterized in the "same way".
EDIT: If you want a measure of "percent error" I suppose you could do something like $$\text{% error}=\frac{\text{magnitude of error}}{\text{original magnitude}}=\frac{\int{||x(t)-y(t)||\,\mathrm{d}t}}{\int{||x(t)||\,\mathrm{d}t}}$$ which is the integral of the difference divided by the arclength of the original path. Since you only have points, you would have to approximate by computing $$\frac{{\Delta t\over 10}\sum{||P_i-B_i||}}{\sum{\sqrt{(x_{i+1}-x_i)^2+(y_{i+1}-y_i)^2}}}$$ where $P_i=(x_i,y_i)$ is the $i$'th point on the path and $B_i$ is the corresponding point on the Bezier curve. So if the Bezier approximation is parameterized with $0\le t\le 1$ then $$B_i=y\left(i{1\over 10}\right)$$ where $y(t)$ is the curve.
Keep in mind that I'm making this up as I go ;) But hopefully you can work with some of these ideas and see if anything fits what you're wanting to get...