give an example of a commutative unitary ring R and two finitely generated R modules M and N such that Hom(M,N) and Hom(N,M) are not isomorphic as R modules.
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Try $R=\mathbb{Z}$, $M=\mathbb{Z}$, $N=\mathbb{Z}_2$. The first $Hom$ is non-trivial, while the second is trivial.
Peter Crooks
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