Injective means that different choice of $M$ will always produce different numbers.
Suppose that
$$
\sum_{n\in M}3^{-n}=\sum_{n\in N}3^{-n}.
$$
Let $k=\min\{n:\ n\in M\setminus N\ \text{ or }n\in N\setminus M\}$. This means that $\{1,\ldots,k-1\}\subset M\cap N$. Thus the all the terms with $n<k$ of the sums are equal. So
$$
\sum_{n\in M,\ n\geq k}3^{-n}=\sum_{n\in N,\ n\geq k}3^{-n}.
$$
Assume that $k\in M$ and $k\not\in N$ (otherwise we exchange roles). Then
$$
3^{-k}+\sum_{n\in M,\ n\geq k+1}3^{-n}=\sum_{n\in N,\ n\geq k+1}3^{-n}.
$$
That is
$$
3^{-k}=\sum_{n\in N,\ n\geq k+1}3^{-n}-\sum_{n\in M,\ n\geq k+1}3^{-n}
\leq\sum_{n=k+1}^\infty3^{-n}=\frac{3^{-k-1}}{1-1/3}=\frac{3^{-k}}2.
$$
We got to a contradiction, that shows that our $k$ cannot exist. So $M=N$.