The Galois Group of some field extension $E/F$ is the group of automorphisms that fix the base field. That is it is the group of automorphisms $\mathrm{Gal}(E/F)$ is formed as follows:
$$
\mathrm{Gal}(E/F) = \{ \sigma \in \mathrm{Aut}(E) \mid \sigma(f) = f \; \forall \; f \in F \}
$$
So you are fairly limited actually with regards to this group. First off you can notice that the only elements that can be permuted around are the elements that are adjoined to form the splitting field. From this you can see that if you join $n$ elements, at max you will then have $n!$ elements in this group, for that's the maximum number of permutations of $n$ things you can have. In other words one can notice that if you adjoin $n$ elements then
$$
\mathrm{Gal}(E/F) \subset S_n
$$
where $S_n$ is the symmetric group of $n$ elements. Naturally you can already see that the maximum number of elements that one would have to adjoin to a base field for a degree $n$ polynomial is $n$ elements, so for any degree $n$ polynomial in a base field $F$ we will have at most $n$ elements adjoined and thus
$$
\mathrm{Gal}(E/F) \subset S_n
$$
By no means are any of the above proofs for any of these facts, but hopefully they provide intuition. In order to prove these facts you have to dive into how Splitting fields are only unique up to isomorphism. Another neat fact is that if $p(x)$ is a seperable polynomial then
$$
\mid \mathrm{Gal}(E/F) \mid = [E : F]
$$
Now let's address the question at hand. You're working with a base field of $\mathbb{Q}$ and with $p(x) = x^2 - 3 \in \mathbb{Q}[x]$. Note that this is degree $2$ so that
$$
\mathrm{Gal}(E/\mathbb{Q}) \subset S_2
$$
where $E$ is the splitting field of $p(x)$. From this you can see that $\mathrm{Gal}$ has at maximum of $2$ elements. Note that it cannot have $1$ element for you must adjoin at least two elements here (both $\pm \sqrt{3}$) so then $\mathrm{Gal}$ must be identically $S_2$.
Another way to go about this is to notice that $p(x)$ is separable so then we have that
$$
\mid \mathrm{Gal}(E/F) \mid = [E : F] = 2
$$
(note showing that showing $[E : F] = 2$ takes some explanation) so then we have the only group with two elements, which is isomorphic to $S_2$.
Lastly from an entirely intuitive perspective we can notice that we need to adjoin two elements to reach the splitting field, namely $\pm \sqrt{2}$ so then the automorphisms can only permute these two elements. Naturally we would have the identity in this group, so some automorphism that sends
$$
\sqrt{3} \to \sqrt{3}
$$
but notice that we can also have another element that sends
$$
\sqrt{3} \to -\sqrt{3}
$$
for this last isomorphism preserves the structure of the splitting field (in higher degree polynomials this can in fact fail. This turns out to be an incredibly deep subject, at least in my opinion - finding the galois group for an arbitrary higher degree polynomial. There is a lot to take into account that at the surface don't appear to be an issue).
A few key points to keep in mind that would have helped me when first starting to learn this stuff:
$\mathrm{Gal}(E/F)$ must fix the base field. I cannot stress this enough. This appears to be the base misunderstanding you have (based on how you asked the question). It cannot, whatsoever, by definition, permute anything in the base field (ever).
$\mathrm{Gal}(E/F) \subset S_n$ it is not necessarily the case that $\mathrm{Gal}(E/F) = S_n$. For me, at first this seemed a little weird; why can't we just permute any of the roots? A good example to think about would be the polynomial $(x^2 -3)(x^2-2)$. We cannot place $\sqrt{3} \to \sqrt{2}$ for then the intermediate fields here would become messed up; that is, $\sqrt{2}$ is a root of $x^2-2$, and in some sense when you send $\sqrt{3} \to \sqrt{2}$ you're implying that $\sqrt{3}$ is also a root, but it actually is not so you cannot have this automorphism in your Galois Group.
This is a hard topic in abstract algebra. It may appear like a simple question at first, but it takes some thought! Don't get too bogged down by all the notation and definitions. At some point I'm sure you'll gain an intuitive understanding for this very difficult subject.
Hopefully this helps, let me know if you need more explanation!