It is known that $\mathbb{E}[X]\leq \mathbb{E}[Y]$. This comes from the definition of expected value on a probability space $(S, \mathcal{G}, P)$ as
$$
\mathbb{E}[X] = \int_{S}XdP,
$$
where the integral is the Lebesgue integral. This property can be verified using the definition of the Lebesgue integral.
Now in your question you have also asked whether $X<Y$ (almost surely) implies $\mathbb{E}[X]<\mathbb{E}[Y]$ (with $<$ instead of $\leq$). This is also true: Suppose that $X<Y$ and $\mathbb{E}[X]=\mathbb{E}[Y]$. Define a random variable $T=Y-X$; this is nonnegative and
$$
0\leq \mathbb{E}[T]=0.
$$
As a result, $T=0$ a.e., therefore, $X=Y$ a.e., which is a contradiction (we have used the fact that for any nonnegative random variable $T$, $\mathbb{E}[T]=0$ implies that $T=0$ a.s.).