Proof of Existence: Let us assume that it was already shown that $(\forall n)((n\ \in\ \omega)\ \ \rightarrow\ \ (n^+\
\neq\ 0))$ which is another way of saying that the natural number $0$ has no immediate predecessor in
$\omega$. So,
what about the nonzero natural numbers---Do they have an immediate predecessor?
Hence, it suffices only to show that:
Each nonzero natural number has an immediate predecessor in $\omega$.
To this end, we conduct induction as follows.
We define a set $M\ \subseteq\ \omega$ consisting of only those nonzero natural numbers which has an immediate predecessor, i.e, $$x\ \in\ M\ \
\leftrightarrow\ \ (x\ \in\ \omega)\ \land\ ((\exists y)(y\ \in\ \omega)\ \ \land\ \ (x\ =\ y^+)\ \land\ (x\ \neq\ \varnothing)).$$Next, define the set $N\ \subseteq\ \omega$ by $N\ =\ M\ \cup\ \{\varnothing\}$. Clearly, by definition of $N$ we have $\varnothing\ \in\ N$. Let $n$ be any non-empty element of $N$ (i.e., $n\ \in\ M$). Then $(n\ \in\ \omega)\ \land\ ((\exists m)(m\ \in\ \omega)\ \land\ (n\ =\ m^+)\ \land\ \ (n\ \neq\ 0))$ holds. But then it follows immediately that: $$(n^+\ \in\ \omega)\ \ \land\ \ ((\exists (m^+)^+)((m^+)^+\ \in\ \omega)\ \ \land\ \ (n^+\ =\ (m^+)^+)\ \ \land\ \ (n^+\ \neq\ 0))$$also holds. This tells us precisely, that $n^+\ \in\ N$ whenever $n\ \in\ N$. Thus, we have shown that the set $N\ =\ M\ \cup\ \{0\}$ is an inductive subset of $\omega$. Therefore, by the Principle of Finite Induction, $N\ =\ \omega$. This complete the Existence part of non-zero natural numbers having an immediate predecessor (or just predecessor).
Predecessors are unique too! This follows from the uniqueness of successors.