I am not quite sure why you might want another approach, seeing that the relevant integral is quite straightforward. But just for the record, here is
an approach using a differential equation and assuming knowledge of the
complex Fourier series of $x$ on the interval $[0,2\pi]$, which is
$$ \pi + \sum_{\stackrel{n=-\infty}{n\not=0}}^\infty \frac{ie^{inx}}{n}\ . $$
Let's look at the function
$$ f(x) = e^x - \frac{e^{2\pi}-1}{2\pi} x\ . $$
This is smooth on $(0,2\pi)$ and satisfies $f(0) = f(2\pi) (= 1)$ so we can
differentiate its Fourier series term-by-term. And it satisfies the differential equation
$$f' -f = \frac{e^{2\pi}-1}{2\pi} (x-1)\ . $$
Suppose now the Fourier series of $f$ is
$$ \sum_{n=-\infty}^\infty c_n e^{inx}\ . $$
Substituting into the differential equation we have
$$ \sum_{n=-\infty}^\infty (in-1) c_n e^{inx}
= \frac{e^{2\pi}-1}{2\pi} \left( \pi - 1 +
\sum_{\stackrel{n=-\infty}{n\not=0}}^\infty \frac{ie^{inx}}{n} \right) $$
so
$$ c_0 = \frac{(e^{2\pi}-1)(1-\pi)}{2\pi} \ , \quad
c_n = \frac{e^{2\pi}-1}{2\pi}\frac{i}{n(in-1)} \quad n\not=0
$$
Finally we use $e^x = f + \frac{e^{2\pi}-1}{2\pi} x $ to get the Fourier series of $e^x$. It is
$$ \left(\frac{(e^{2\pi}-1)(1-\pi)}{2\pi} +
\sum_{\stackrel{n=-\infty}{n\not=0}}^\infty
\frac{e^{2\pi}-1}{2\pi}\frac{i}{n(in-1)} e^{inx}\right)
+ \frac{e^{2\pi}-1}{2\pi}\left(
\pi + \sum_{\stackrel{n=-\infty}{n\not=0}}^\infty \frac{ie^{inx}}{n}
\right)
$$
which simplifies to
$$ \frac{e^{2\pi}-1}{2\pi}
\sum_{n=-\infty}^\infty
\frac{e^{inx}}{1-in}
$$