Let's try an inductive proof. We first prove the result for positive integers $n$ by using induction on $n$. For $n = 1$ we can see that $$\lim_{x \to 1}\frac{x^{n} - 1}{x - 1} = \lim_{x \to 1}\frac{x - 1}{x - 1} = 1 = n$$ so that the result is verified for $n = 1$. Let's assume it is true for $n = m$ and we try to establish it for $n = m + 1$. We have $$\begin{aligned}L\,&= \lim_{x \to 1}\frac{x^{n} - 1}{x - 1}\\
&= \lim_{x \to 1}\frac{x^{m + 1} - 1}{x - 1}\\
&= \lim_{x \to 1}\frac{x^{m + 1} - x + x - 1}{x - 1}\\
&= \lim_{x \to 1}\frac{x(x^{m} - 1) + x - 1}{x - 1}\\
&= \lim_{x \to 1}x\cdot\frac{x^{m} - 1}{x - 1} + 1\\
&= 1\cdot m + 1 = m + 1 = n\end{aligned}$$ so that the result is true for $n = m + 1$ as well. By induction it is true for all positive integers $n$.
To handle negative integers we again apply induction. This time we assume that result holds for some integer $n = m$ and show that it holds for $n = m - 1$ also. We have $$\begin{aligned}L\,&= \lim_{x \to 1}\frac{x^{n} - 1}{x - 1}\\
&= \lim_{x \to 1}\frac{x^{m - 1} - 1}{x - 1}\\
&= \lim_{x \to 1}\frac{x^{m} - x}{x(x - 1)}\\
&= \lim_{x \to 1}\frac{x^{m} - 1 - (x - 1)}{x(x - 1)}\\
&= \lim_{x \to 1}\frac{1}{x}\cdot\frac{x^{m} - 1}{x - 1} - \frac{1}{x}\\
&= 1\cdot m - 1 = m - 1 = n\end{aligned}$$ So we can always go from $n = m$ to the previous integer $n = m - 1$. We know that result is true for $n = 1$ so it is true for previous integer $0$ and so true for previous integer $-1$ and so on. By induction it is true for all negative integers $n$ (as well as for $n = 0$).
Other answers given above are quite standard and well known and I have tried to present a different approach. Also all the other answers seem to have left the case when $n < 0$ although this is a simple extension once the result is established for $n > 0$.