Let $X$ be the intersection of the lines $MN$ and $BC$. Here is a picture:

Apply the theorem of Menelaus for the triangles $\Delta ABD$, $\Delta ADC$ to get (using sign conventions for proportions of two segments on the same line):
$$
\begin{aligned}
1 &=
\frac{MB}{MA}\cdot \underbrace{\frac{GA}{GD}}_{=-2}\cdot \frac{XD}{XB}\ ,
\\
1 &=
\frac{NC}{NA}\cdot \underbrace{\frac{GA}{GD}}_{=-2}\cdot \frac{XD}{XC}\ ,
\qquad\text{ and from here}
\\[3mm]
\frac{MB}{MA} + \frac{NC}{NA}
&=-\frac 12\left( \frac{XB}{XD} + \frac{XC}{XD}\right)
= -\frac 12\cdot\frac{XB+XC}{XD}= -\frac 12\cdot\frac{2XD}{XD}
=\boxed{\ -1\ }\ .
\end{aligned}
$$
$\square$
Note: By sign convention we have
$\displaystyle
\frac{MB}{MA} = -\frac{MB}{AM}$, and
$\displaystyle
\frac{NC}{NA} = -\frac{NB}{AN}$, making the sign a plus one for the sum in the question.