Here are two different options, if I am understanding what you want correctly. Say your smallest integer is $a$ and your largest $b$,
\begin{equation}
f(x) = b - \frac{b-a}{1 + e^{(x-(b+a)/2)}}
\end{equation}
which will give $\{1.099, 1.264 1.683, 2.642, 4.398, 6.602, 8.358, 9.317, 9.736, 9.901\}$ for the inputs 1 through 10. Here is a graph

This actually does give "exponential" behavior in the middle, and you can control the steepness in the middle of the range by multiplying the $(x-5.5)$ in the exponent by a factor greater than one to make it "steeper" and less than one to make it less "steep".
Another option is to use something like a quintic polynomial, which isn't exponential but would seem to give the behavior you are looking for. For instance,
\begin{equation}
p(y) = 54y^5 - 135y^4 + 90y^3 + 1
\end{equation}
with $y = (x-1)/9$ and $x$ your input integers 1 through 10,
yields the outputs $\{1,1.1038,1.6877,2.889,4.570,6.430,8.111,9.312,9.896,10\}$.
Here is a graph of the polynomial:
To solve for the polynomial coefficients, just set up the matrix system
\begin{equation}
\begin{bmatrix} 1 & 0 & 0 & 0 & 0 & 0 \\
0 & 1 & 0 & 0 & 0 & 0 \\
0 & 0 & 2 & 0 & 0 & 0 \\
1 & 1 & 1 & 1 & 1 & 1 \\
0 & 1 & 2 & 3 & 4 & 5 \\
0 & 0 & 2 & 6 & 12 & 20 \end{bmatrix} c =
\begin{bmatrix}
\text{min output} \\ 0 \\ 0 \\ \text{max output} \\ 0 \\ 0
\end{bmatrix}
\end{equation}
The coefficients $c_i$ form the polynomial $p(y) = c_0 + c_1 y + ... + c_5 y^5$. Then use the transformation $y = (x - 1)/(b - a)$, and your input integers are $x$ and your output values are $p(y(x))$.
Apologies for being unclear. To clarify, the input set should be consecutive natural numbers.
– Alex Lin Aug 21 '14 at 20:14