We want that
$$(z_1+z_2+2a)(z_1-z_2)+a(\bar z_1-\bar z_2)=0,\quad z_1,z_2\in D:=\bigl\{z\>\bigm|\>|z|<1\bigr\}\tag{1}$$
together imply $z_1=z_2$.
Write
$$z_1+z_2=:2z, \quad z_1-z_2=\rho\>e^{i\phi}\ .$$
Then $z\in D$, and the pair $(z, \rho e^{i\phi})$ determines $z_1$ and $z_2$. Rewriting $(1)$ in terms of the new variables we obtain the equation
$$2(z+a)\rho e^{i\phi}+a\rho e^{-i\phi}=0\ .\tag{2}$$
When $\rho\ne0$ this is equivalent to
$$z=-a-{a\over2}e^{-2i\phi}\ .\tag{3}$$
From $(3)$ we draw the following conclusions:
(I)$\quad$ If the circle with center $-a$ and radius ${|a|\over2}$ intersects $D$ in a point $z$ then $(2)$ has a solution $(z,\rho e^{i\phi})$ with $z\in D$ and arbitrary $\rho>0$. If $\rho$ is choosen sufficiently small the two corresponding points $z_1$, $z_2$ both lie in $D$, are different, and satisfy $(1)$. It follows that such an $a$ is forbidden.
(II)$\quad$ If the circle with center $-a$ and radius ${|a|\over2}$ does not intersect $D$ then $(2)$ has no solutions $(z,\rho e^{i\phi})$ with $z\in D$ and $\rho>0$. It follows that such an $a$ is allowed.
On account of (I) and (II) the set of allowed values for $a$ is characterized by $|a|\geq2$.