The Killing form is defined by $K(x,y) = \text{tr}(\text{ad} x, \text{ad} y)$, right? In this lecture, we assume that $\{x_1, ... , x_n\}$ is a basis for $g$ and $\{y_1, ... ,y_n\}$ is a dual basis with respect to the Killing form...which is equivalent to saying $K(x_i, y_j) = \delta_{ij}$ for $1 \leq i, j \leq n$.
This is kind of confusing...we know that the dual of $g$ is the set of linear functionals $f: g \rightarrow k$, right? So a basis of that is a set of functions from $g$ to $k$. However, we know that the domain of the Killing form is $g \times g$. How does that make sense?