One reason to care about mathematical structures is they allow us to prove things "once and for all." For example, we can prove that if a poset has all bounded-above non-empty joins, then it has all bounded-below non-empty meets, and vice versa. Therefore, since $\mathbb{R}$ can be viewed as a poset with respect to the usual order relation, and since the completeness axiom tells us that $\mathbb{R}$ has all bounded-above non-empty joins (i.e. suprema), hence our theorem tells us that it has all bounded-below non-empty meets (i.e. infima). We don't have to "re-prove" this for the special case of $\mathbb{R}$.
There is at least one more reason to care about mathematical structures, namely the homomorphisms. At a basic level, homomorphisms are important because they preserve lots of goodies. For example, if:
- $X$ and $Y$ are monoids,
- $\varphi : X \rightarrow Y$ is a monoid homomorphism
- $x,x' \in X$ are elements
then $$xx' = e_X \;\implies\; f(x)f(x') = e_Y.$$
So monoid homomorphisms preserve inverses, and therefore, they preserve invertibility.
Taking a more sophisticated viewpoint, structures and their homomorphisms tend to form into categories. For example, there is a category $\mathbf{Grp}$ whose objects are groups and whose arrows are group homomorphisms. There is also usually a so-called forgetful functor to $\mathbf{Set}$ (see here). A major application of this occurs in abstract algebra, whereby we can describe the construction of free algebras as left-adjoint to the forgetful functor. This leads to the idea of presentations; e.g. we can present a group by generators and relations.