Let $H$ be the orthocenter of $ABC$. Then
$$ d(H,BC) = 2R\cos B\cos C $$
hence:
$$ \sum_{cyc} 2R a\cos B\cos C = 2S. $$
If $ABC$ is an acute triangle, then $\cos A,\cos B,\cos C>0$ and $a,b,c < 2R$, hence:
$$ \sum_{cyc} a^2\cos B\cos C < \sum_{cyc} 2R a\cos B\cos C = 2S. $$
However, if $ABC$ is an obtuse triangle, the given inequality does not hold: consider, for instance, $(a,b,c)=(\sqrt{3},1,1)$, so that $(A,B,C)=(120^\circ,30^\circ,30^\circ)$,
$$\sum_{cyc}a^2\cos B\cos C = \frac{9}{4}-\frac{\sqrt{3}}{2},\qquad 2S=\frac{\sqrt{3}}{2}.$$