The natural map goes this way $\Gamma(E) \otimes \Gamma(F) \to \Gamma(E\otimes F)$.
Injectiveness is not a problem.
Surjectiveness is. Think of compact connected complex manifold, $E$ a bundle with a $0$ space of global sections, while $E\otimes F$ has lots of global sections.
However in the smooth or topological category things are OK because it is true for trivial bundles and it is true for a direct sum if and only if it is true for summands. Moreover, every bundle is a direct summand of a trivial one, like @anomaly: indicated. In fact, bundles are equivalent to finitely generated projective module over the ring of functions on the manifold (Swan's theorem) and things work fine for tensor products.
http://math.stackexchange.com/questions/1323787/what-is-the-relation-between-c-infty-linear-and-tensorial/1323833#1323833
– Fallen Apart Sep 07 '15 at 18:13