Let $w\in V\setminus\{0\}$, $T_i:V\longrightarrow F$ be given by $T_i(v) = {\langle v, w\rangle}_i$ for $i \in \{1,2\}$ and $T = T_1 + T_2$.
Notice that $T, T_1$ and $T_2$ are linear.
$\quad(1)$ $\;$ If $T\equiv 0$ we can take $c=-1$.
$\quad(2)$ $\;$ Otherwise, since $T$ is not identically $0$, $\ker T\subsetneq V$.
We may hence write
$$V = (\ker T) \oplus W,\tag{1}$$
where $\dim W > 0$.
$\quad\quad(2.1)$ $\;$If $\dim W = 1$, say $W=\text{span}(u)$, we can take $c = T_1(u)/T_2(u)$.
$\quad\quad(2.2)$ $\;$If $\dim W \geqslant 2$, we may choose a linearly indepenent set $\{u, v\} \subset W$ with $T(u) = T(v) = 1$.
Then $T_i(u), T_i(v)\neq 0$ for $i=1,2$ and
\begin{align}
&\left\{\begin{array}{c}
T_1(u)+T_2(u) = 1\\
T_1(v)+T_2(v) = 1
\end{array}\right.
\\\implies
&\left\{\begin{array}{c}
\frac{T_1(u)}{T_2(u)}= \frac1{T_2(u)} - 1\\
\frac{T_1(v)}{T_2(v)}= \frac1{T_2(v)} - 1
\end{array}\right.
\end{align}
If we had $T_1 = c\,T_2$, then necessarily
$$\frac1{T_2(u)} - 1 = \frac1{T_2(v)} - 1 \implies T_2(u) = T_2(v) \,\text{ and }\, T_1(u) = T_1(v)$$
In particular, we'd have $u-v \in \ker T_1 = \ker T_2\subset \ker T$.
But since the sum in $(1)$ is direct, this would mean $u-v = 0$, contradicting the linear independence of $\{u,v\}$.
It follows that either $\dim W \geqslant 2$ can never happen, or else $T_1\neq cT_2$ when $\dim W \geqslant 2$.
Notice that because of the rank-nullity theorem, this issue can only ever arise when $V$ is infinite dimensional.
Indeed, when $V$ is finite dimensional, the theorem guarantees that
$$\dim W = \dim V - \dim \ker T = \dim \text{Im } T \leqslant 1.$$