$$
f(x) = x-e^{-x}
$$
is such a function. Since $f''(x) = -e^{-x}$ is always negative, it is strictly concave, and it's not hard to show it hits every real.
Even better,
$$
f(x) = 2x -\sqrt{1+3x^2}
$$
has $f''(x) = -3(1+3x^2)^{-3/2} < 0$ everywhere and the explicit inverse $f^{-1}(x) = 2x+\sqrt{1+3x^2}$, clearly defined for all $x$.
EDIT: Since it was requested in the comments, here is a plot of this function and its inverse:

Note that even though the growth rate for positive $x$ is slow, the function is asymptotically linear (with slope $2-\sqrt{3}\approx 0.268$) and thus unbounded.